Theory
Decimals are numbers with digits after the decimal point. The first digit after the decimal point is tenths, the second is hundredths, and the third is thousandths.
When comparing decimals, line up the decimal points. This keeps ones with ones, tenths with tenths, and hundredths with hundredths.
You may add zeros to the end of a decimal to help compare it. For example, 4.5 is the same value as 4.50, but 4.05 is different.
Do not compare decimals by counting the number of digits after the decimal point. 0.8 is bigger than 0.75 even though 0.75 has more decimal digits.
Compare from left to right, just like whole numbers. The first place value where the digits differ decides the larger decimal.
For Edexcel Foundation questions, a common trap is mixing money-style thinking with ordinary decimals. Always use place value unless the question is about pounds and pence.