Theory
Basic trigonometry uses right-angled triangles. The sine rule and cosine rule are for triangles that do not have a right angle.
Start by labelling the triangle. A side and its opposite angle are a matching pair. Side a is opposite angle A, side b is opposite angle B, and side c is opposite angle C.
Use the sine rule when you have an opposite side-angle pair and you need another side or another angle.
Use the cosine rule when you have two sides and the included angle, or when you have all three sides and need an angle.
Use area = 1/2ab sin C when you know two sides and the included angle between them.
Higher note: the hardest mark is often choosing the correct rule. The calculator work is usually straightforward once the rule is chosen.
For Edexcel marks, write the formula substitution before rounding the answer.